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Beilstein J. Org. Chem. 2018, 14, 1546–1553, doi:10.3762/bjoc.14.131
Graphical Abstract
Figure 1: Selected ferrocene-based ligands and organocatalysts.
Scheme 1: Scope of substituted dioxazolones 2.
Scheme 2: C–H Amidation of arylated ferrocenes 1.
Scheme 3: Thiocarbonyl-assisted C–H amidation.
Scheme 4: H/D Exchange reactions.
Scheme 5: Intermolecular competition experiments.
Scheme 6: Synthesis of aminoketone 4aa.
Scheme 7: Mechanochemical ferrocene C–H nitrogenation.
Beilstein J. Org. Chem. 2014, 10, 276–281, doi:10.3762/bjoc.10.23
Figure 1: Structure of decandrinin (1).
Figure 2: Selected 1H–1H COSY and HMBC correlations for decandrinin (1).
Figure 3: Diagnostic NOE interactions for decandrinin (1, B97D/TZVP-optimized structure): arbitrarily the 5R,9...
Figure 4: Determination of the absolute configuration of decandrinin (1) by comparing the calculated CD spect...
Scheme 1: Proposed biosynthetic pathway for decandrinin (1).
Beilstein J. Org. Chem. 2009, 5, No. 53, doi:10.3762/bjoc.5.53
Scheme 1: Identification of optimal chiral ligand for iridium-catalyzed asymmetric ring-opening of oxabenzono...
Figure 1: ORTEP plot for 3f.
Scheme 2: Proposed mechanism for the ARO of oxabenzonorbornadiene 1a with secondary amine nucleophiles.